汞元素在環(huán)境中以無機(jī)形態(tài)(Hg~0,Hg~(2+))和有機(jī)形態(tài)(CH_3Hg~+,C_2H_5Hg~+等)廣泛存在。雖然含量甚微,但是由于其毒性大,早已被多國列入重點(diǎn)優(yōu)先控制的污染物。汞元素在自然界中的賦存形態(tài)不同,毒性和環(huán)境行為亦不相同。研究表明,烷基汞主要包括甲基汞和乙基汞,是一類具有嚴(yán)重生物毒性的有機(jī)金屬化合物,毒性要比無機(jī)汞大得多,其中毒性最強(qiáng)的是甲基汞。甲基汞(CH_3Hg~+)容易穿過血腦屏障對(duì)中樞神經(jīng)系統(tǒng)造成嚴(yán)重的永久性損傷。
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浩瀚色譜（山東）應(yīng)用技術(shù)開發(fā)有限公司，根據(jù)巰基棉在一定酸性條件下能定量吸附烷基汞的原理，利用多通道并聯(lián)的同相萃取裝置，采用氣相色譜法測定廢水中烷基汞，并通過質(zhì)量控制手段對(duì)方法進(jìn)行研究。研究發(fā)現(xiàn)方法線性較好，甲基汞和乙基汞標(biāo)準(zhǔn)曲線線性均在0.999以上；當(dāng)采樣體積為200 mL時(shí)，甲基汞和乙基汞檢出限分別為0.43和0.53 ng/L，兩種化合物的精密度分別為2.8%和3.9%，回收率分別為87.2%和85.9%;另外采用農(nóng)殘級(jí)或色譜級(jí)的甲苯、洗脫液(鹽酸)經(jīng)溶劑萃取一次后，可滿足方法的空白值要求。
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名稱：烷基汞專用柱
規(guī)格：30m*0.32mm
型號(hào)：HH-Alkyl-HG-30
應(yīng)用：水質(zhì)，環(huán)境中烷基汞測定 氣相色譜法
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氯化甲基汞和氯化乙基汞，峰形尖銳、對(duì)稱，，重復(fù)性好，定量準(zhǔn)確。
類似：ULBON HR-Thermon-HG 15m x 0.53mm
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Mercury is widely present in the environment in inorganic forms (Hg~0, Hg~(2+)) and organic forms (CH3Hg+, C-2H5Hg+, etc.). Although the content is very small, due to its high toxicity, it has already been listed as a key priority pollutant for control by many countries. The occurrence forms of mercury in nature are different, and its toxicity and environmental behavior are also different. Research has shown that alkyl mercury mainly includes methylmercury and ethyl mercury, which are a class of organometallic compounds with severe biological toxicity. Their toxicity is much greater than inorganic mercury, with methylmercury being the most toxic. Methylmercury (CH3Hg+) can easily cross the blood-brain barrier and cause serious permanent damage to the central nervous system.
Haohan Chromatography (Shandong) Application Technology Development Co., Ltd., based on the principle that thiol cotton can quantitatively adsorb alkylmercury under certain acidic conditions, uses a multi-channel parallel in-phase extraction device to determine alkylmercury in wastewater by gas chromatography, and studies the method through quality control measures. Research has found that the method has good linearity, with standard curves for methyl mercury and ethyl mercury both showing linearity above 0.999; When the sampling volume is 200 mL, the detection limits of methyl mercury and ethyl mercury are 0.43 and 0.53 ng/L, respectively. The precision of the two compounds is 2.8% and 3.9%, and the recovery rates are 87.2% and 85.9%, respectively; In addition, using pesticide residue grade or chromatographic grade toluene and eluent (hydrochloric acid) for solvent extraction once can meet the blank value requirements of the method.
Name: Alkyl mercury dedicated column
Specification: 30m * 0.32mm
Model: HH-Alkyl-HG-30
Application: Water quality, determination of alkylmercury in the environment, gas chromatography method
Methylmercury chloride and ethyl mercury chloride have sharp and symmetrical peaks, good repeatability, and accurate quantification.
Similar to: ULBON HR Thermon HG 15m x 0.53mm
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